Search results for "Langmuir-Hinshelwood kinetics"

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Two-Dimensional Modeling of an Externally Irradiated Slurry Photoreactor

2013

Abstract A batch cylindrical photocatalytic reactor, externally irradiated by 1–6 UV fluorescent lamps and containing a stirred slurry of polycrystalline TiO2, was modeled by coupling a modified Langmuir–Hinshelwood kinetics together with a two-dimensional light intensity field. The radiation field has been determined on the main assumptions of diffuse radiation, isotropic scattering and negligible backward reflected photon flow. The model has been applied to the photocatalytic oxidation of organic substrates which do not undergo homogeneous photochemical degradation. The model is characterized by the following four parameters: the kinetic constants of substrate adsorption, desorption and d…

Settore ING-IND/24 - Principi Di Ingegneria ChimicaMaterials sciencePhotonLangmuir-Hinshelwood kineticsGeneral Chemical EngineeringKineticsAnalytical chemistryexternally irradiated photoreactorLight intensityphotoreactor modelingAdsorptionDesorptionPhotocatalysisSlurrySettore CHIM/07 - Fondamenti Chimici Delle TecnologieIrradiationInternational Journal of Chemical Reactor Engineering
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